Issue 22, 2004
From the journal:

Chemical Communications

Bidentate amidineligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons†

Masao Aoki,a   Motomu Kaneko,a   Sawa Izumi,a   Kazutoshi Ukaia  and  Nobuharu Iwasawa*a  

* Corresponding authors

a Department of Chemistry, Tokyo Institute of Technology, 2-12-1 E1-2, O-okayama, Japan
E-mail: niwasawa@chem.titech.ac.jp
Fax: (+81) 3 5734 2931
Tel: (+81) 3 5734 2746

Abstract

Novel bidentate amidines were designed and synthesized as easily available electron-donating N-ligands for Ni0-mediated coupling of carbon dioxide with alkynes or allenes, and high regioselectivity was achieved even for the carboxylation of aryl substituted internal alkynes.

Graphical abstract: Bidentate amidine ligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons

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Article information

DOI
https://doi.org/10.1039/B411802B
Article type
Communication
Submitted
02 Aug 2004
Accepted
26 Aug 2004
First published
29 Sep 2004

Chem. Commun., 2004, 2568-2569

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Bidentate amidine ligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons

M. Aoki, M. Kaneko, S. Izumi, K. Ukai and N. Iwasawa, Chem. Commun., 2004, 2568 DOI: 10.1039/B411802B

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