Issue 21, 2004
From the journal:

Chemical Communications

Enantioselective synthesis of allenyl carbinols by the CBS reduction in nitroethane: dramatic solvent effect for reactivity and enantioselectivity†

Chan-Mo Yu,*a   Chunsan Kima  and  Jae-Hong Kweona  

* Corresponding authors

a Department of Chemistry and Lab for Metal-Catalysed Reactions, Sungkyunkwan University, Suwon, Korea
E-mail: cmyu@chem.skku.ac.kr
Fax: +82 31 290 7075
Tel: +82 31 290 7067

Abstract

Dramatic solvent effect of nitroethane was observed in the catalytic asymmetric reductions of allenyl ketones and α,β-ynones using the oxazaborolidine cayalyst to yield the corresponding alcohols in high levels of enantioselectivity.

Graphical abstract: Enantioselective synthesis of allenyl carbinols by the CBS reduction in nitroethane: dramatic solvent effect for reactivity and enantioselectivity

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Article information

DOI
https://doi.org/10.1039/B407387H
Article type
Communication
Submitted
18 May 2004
Accepted
05 Aug 2004
First published
13 Sep 2004

Chem. Commun., 2004, 2494-2495

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Enantioselective synthesis of allenyl carbinols by the CBS reduction in nitroethane: dramatic solvent effect for reactivity and enantioselectivity

C. Yu, C. Kim and J. Kweon, Chem. Commun., 2004, 2494 DOI: 10.1039/B407387H

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