Issue 9, 2004
From the journal:

Chemical Communications

Carbon monoxide solubility in ionic liquids: determination, prediction and relevance to hydroformylation†

C. André Ohlin,a   Paul J. Dysona  and  Gábor Laurenczy*a  

* Corresponding authors

a Institut des Sciences et Ingénerie Chimiques (ISIC), Ecole Polytechnique Fédérale de Lausanne, EPFL-BCH, CH-1015 Lausanne, Switzerland
E-mail: gabor.laurenczy@epfl.ch

Abstract

The solubility of carbon monoxide in 37 ionic liquids and in some organic solvents has been determined using high-pressure 13C NMR spectroscopy; a method for predicting the CO solubility is demonstrated, and it was shown that the rate of the hydroformylation of 5-hexen-2-one does not correlate with the CO solubility, as expected from the determined relative solubility of CO compared to H2.

Graphical abstract: Carbon monoxide solubility in ionic liquids: determination, prediction and relevance to hydroformylation

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Article information

DOI
https://doi.org/10.1039/B401537A
Article type
Communication
Submitted
02 Feb 2004
Accepted
02 Mar 2004
First published
01 Apr 2004

Chem. Commun., 2004, 1070-1071

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Carbon monoxide solubility in ionic liquids: determination, prediction and relevance to hydroformylation

C. A. Ohlin, P. J. Dyson and G. Laurenczy, Chem. Commun., 2004, 1070 DOI: 10.1039/B401537A

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