Mn3(HCOO)6: a 3D porous magnet of diamond framework with nodes of Mn-centered MnMn4 tetrahedron and guest-modulated ordering temperature

Zheming Wang; Bin Zhang; Hideki Fujiwara; Hayao Kobayashi; Mohamedally Kurmoo

doi:10.1039/B314221C

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Mn₃(HCOO)₆: a 3D porous magnet of diamond framework with nodes of Mn-centered MnMn₄ tetrahedron and guest-modulated ordering temperature†

Zheming Wang,*^ab Bin Zhang,^a Hideki Fujiwara,^a Hayao Kobayashi*^a and Mohamedally Kurmoo^c

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* Corresponding authors

^a Institute for Molecular Science and CREST, Japan, Science and Technology Coorporation, Okazaki 444-8585, Japan
E-mail: hayao@ims.ac.jp
Fax: +81-564-54-2254
Tel: +81-564-54-2254

^b College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China
E-mail: wzm@chem.pku.edu.cn
Fax: +8610-62751708
Tel: +8610-62755926

^c Institut de Physique et Chimie des Matériaux de Strasbourg, CNRS-UMR 7504, 23 Rue de Loess, BP 43, F-67034 Strasbourg Cedex2, France

Abstract

Mn₃(HCOO)₆, a 3D highly stable and flexible porous diamondoid framework based on Mn-centered MnMn₄ tetrahedral nodes, exhibits a wide spectrum of guest inclusion behaviour and long-range magnetic ordering with guest-modulated critical temperature.

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Article information

DOI: https://doi.org/10.1039/B314221C
Article type: Communication
Submitted: 07 Nov 2003
Accepted: 04 Dec 2003
First published: 21 Jan 2004

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Chem. Commun., 2004, 416-417

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Mn₃(HCOO)₆: a 3D porous magnet of diamond framework with nodes of Mn-centered MnMn₄ tetrahedron and guest-modulated ordering temperature

Z. Wang, B. Zhang, H. Fujiwara, H. Kobayashi and M. Kurmoo, Chem. Commun., 2004, 416 DOI: 10.1039/B314221C

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Chemical Communications