Issue 2, 2004
From the journal:

Chemical Communications

First Br4 four centre–six electron and Se2Br5 seven centre–ten electron bonds in nonionic bromine adducts of selenanthrene

Warô Nakanishi,*a   Satoko Hayashi,a   Shigehiro Yamaguchib  and  Kohei Tamaob  

* Corresponding authors

a Department of Material Science and Chemistry, Faculty of Systems Engineering, Wakayama University, 930 Sakaedani, Wakayama 640-8510, Japan
E-mail: nakanisi@sys.wakayama-u.ac.jp
Fax: +81 73 457 8253
Tel: +81 73 457 8252

b Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan

Abstract

Extended hypervalent Br4 4c–6e and Se2Br5 7c–10e bonds are detected in nonionic bromine adducts of selenanthrene, where the four Br4 and seven Se2Br5 atoms align linearly.

Graphical abstract: First Br4 four centre–six electron and Se2Br5 seven centre–ten electron bonds in nonionic bromine adducts of selenanthrene

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Article information

DOI
https://doi.org/10.1039/B310655A
Article type
Communication
Submitted
03 Sep 2003
Accepted
13 Nov 2003
First published
05 Dec 2003

Chem. Commun., 2004, 140-141

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First Br4 four centre–six electron and Se2Br5 seven centre–ten electron bonds in nonionic bromine adducts of selenanthrene

W. Nakanishi, S. Hayashi, S. Yamaguchi and K. Tamao, Chem. Commun., 2004, 140 DOI: 10.1039/B310655A

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