Issue 14, 2003
From the journal:

Chemical Communications

[{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence†

Eduardo J. Fernández,a   Antonio Laguna,*b   José María López-de-Luzuriaga,a   M. Elena Olmosa  and  Javier Péreza  

* Corresponding authors

a Departamento de Química, Universidad de La Rioja, Grupo de Síntesis Química de La Rioja, UA-CSIC, Madre de Dios 51, E-26004 Logroño, Spain

b Departamento de Química Inorgánica-ICMA, Universidad de Zaragoza-CSIC, E-50009 Zaragoza, Spain
E-mail: alaguna@posta.unizar.es
Fax: 34 976761187
Tel: 34976761185

Abstract

The complex [{AuTl(C6Cl5)2(toluene)}2(dioxane)] displays a structure with the thallium(I) center in an unprecedented trigonal planar environment, showing the shortest Au–Tl interaction ever found, a toluene molecule in a η6-mode and the “disappearance” of the Tl(I) inert pair, usually stereochemically active. These characteristics are responsible for its unusual luminescent behaviour.

Graphical abstract: [{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence

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Article information

DOI
https://doi.org/10.1039/B304835G
Article type
Communication
Submitted
30 Apr 2003
Accepted
30 May 2003
First published
16 Jun 2003

Chem. Commun., 2003, 1760-1761

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[{AuTl(C6Cl5)2(toluene)}2(dioxane)]: A striking structure that leads to a blue luminescence

E. J. Fernández, A. Laguna, J. M. López-de-Luzuriaga, M. Elena Olmos and J. Pérez, Chem. Commun., 2003, 1760 DOI: 10.1039/B304835G

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