A new class of C1-symmetric monosulfoximine ligands for enantioselective hetero Diels–Alder reactions

Carsten Bolm; Marinella Verrucci; Oliver Simic; Pier Giorgio Cozzi; Gerhard Raabe; Hiroaki Okamura

doi:10.1039/B309556H

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A new class of C₁-symmetric monosulfoximine ligands for enantioselective hetero Diels–Alder reactions†

Carsten Bolm,*^a Marinella Verrucci,^a Oliver Simic,‡^a Pier Giorgio Cozzi,^b Gerhard Raabe^a and Hiroaki Okamura^a

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* Corresponding authors

^a Institute of Organic Chemistry, RWTH Aachen Professor-Pirlet-Strasse 1, D-52056 Aachen, Germany
E-mail: Carsten.Bolm@oc.rwth-aachen.de
Fax: +49 241 809 2391
Tel: +49 241 809 4675

^b Dipartimento di Chimica, G. Ciamician, Via Selmi 2, 40126 Bologna, Italy

Abstract

Quinoline-based C₁-symmetric sulfoximines have been used as chiral ligands in copper-catalyzed asymmetric hetero Diels–Alder reactions leading to cycloadducts with up to 96% ee.

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Article information

DOI: https://doi.org/10.1039/B309556H
Article type: Communication
Submitted: 11 Aug 2003
Accepted: 22 Sep 2003
First published: 13 Oct 2003

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Chem. Commun., 2003, 2826-2827

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A new class of C₁-symmetric monosulfoximine ligands for enantioselective hetero Diels–Alder reactions

C. Bolm, M. Verrucci, O. Simic, P. G. Cozzi, G. Raabe and H. Okamura, Chem. Commun., 2003, 2826 DOI: 10.1039/B309556H

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