Issue 18, 2003
From the journal:

Chemical Communications

New routes to high nuclearity cages: dimerisation of a manganese triangle viasolvothermal synthesis

David M. Low,a   Euan K. Brechin,*a   Madeleine Helliwell,a   Talal Mallah,b   Eric Rivièreb  and  Eric J. L. McInnes*a  

* Corresponding authors

a Department of Chemistry, The University of Manchester, Oxford Road, Manchester, UK
E-mail: euan.k.brechin@man.ac.uk, eric.mcinnes@man.ac.uk
Fax: +44) 161-275-4616
Tel: (+44) 161-275-7857

b Laboratoire de Chimie Inorganique, UMR CNRS 8613, Université de Paris-Sud, 91405 Orsay, France

Abstract

Heating [Mn3O(O2CPh)6(py)2(H2O)] in MeCN at 100 °C for 12 hours in a sealed Teflon container produces the hexanuclear species [Mn6O2(O2CPh)12(py)2]: dimerisation of the triangle occurs via solvent loss and ligand rearrangement.

Graphical abstract: New routes to high nuclearity cages: dimerisation of a manganese triangle via solvothermal synthesis

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Article information

DOI
https://doi.org/10.1039/B305245A
Article type
Communication
Submitted
09 May 2003
Accepted
29 Jul 2003
First published
06 Aug 2003

Chem. Commun., 2003, 2330-2331

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New routes to high nuclearity cages: dimerisation of a manganese triangle via solvothermal synthesis

D. M. Low, E. K. Brechin, M. Helliwell, T. Mallah, E. Rivière and E. J. L. McInnes, Chem. Commun., 2003, 2330 DOI: 10.1039/B305245A

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