Unusual Pd-catalyzed cyclizations of unsymmetrical allylic acetates, where the nucleophile is tethered to the central allyl carbon, are shown for the first time to be remarkably controlled by heteroatom-mediated preassociation of the reacting partners.
M. E. Krafft and M. C. Lucas, Chem. Commun., 2003, 1232 DOI: 10.1039/B302342G
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