Issue 10, 2003
From the journal:

Chemical Communications

The truly symmetrical doubly-bridging mode of trimethylphosphine in a dinuclear rhodium complex†

Thomas Pechmann,a   Carsten D. Brandta  and  Helmut Werner*a  

* Corresponding authors

a Institut für Anorganische Chemie der Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany
E-mail: helmut.werner@mail.uni-wuerzburg.de;
Fax: ++49-931-888-4623

Abstract

The dinuclear complex [Rh2I2(μ-CPh2)2(μ-PMe3)] was prepared from the Rh2(acac)2 counterpart and Me3SiI and shown crystallographically to contain the PMe3 ligand in a truly symmetrical bridging position; a new synthetic route to migrate more bulky phosphines such as PPh3 and PiPr3 from a terminal into a bridging site is also described.

Graphical abstract: The truly symmetrical doubly-bridging mode of trimethylphosphine in a dinuclear rhodium complex

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B301251D
Article type
Communication
Submitted
30 Jan 2003
Accepted
14 Mar 2003
First published
16 Apr 2003

Chem. Commun., 2003, 1136-1137

Permissions

Request permissions

The truly symmetrical doubly-bridging mode of trimethylphosphine in a dinuclear rhodium complex

T. Pechmann, C. D. Brandt and H. Werner, Chem. Commun., 2003, 1136 DOI: 10.1039/B301251D

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements