Issue 4, 2003
From the journal:

Chemical Communications

The first NH aldimineorganometallic compound. Isolation and crystal structure†

Joan Albert,a   J. Magali Cadena,a   Asensio González,b   Jaume Granell,*a   Xavier Solansc  and  Mercè Font-Bardiac  

* Corresponding authors

a Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, Barcelona, Spain
E-mail: jaume.granell@qi.ub.es
Fax: 34 93 4907725

b Laboratorio de Química Orgánica, Facultat de Farmàcia, Universitat de Barcelona, Pl. Pius XII, s/n, Barcelona, Spain

c Departament de Cristal.lografia i Dipòsits Minerals, Universitat de Barcelona, Martí i Franquès, s/n, Barcelona, Spain

Abstract

The first NH aldimine organometallic derivative is unexpectedly formed by the cleavage of the nitrogen–carbon bond of the amino acid fragment of the Schiff base 2,4,6-Me3C6H2CH[double bond, length as m-dash]NCH(CH2Ph)COOEt when the imine is treated with palladium acetate.

Graphical abstract: The first NH aldimine organometallic compound. Isolation and crystal structure

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Article information

DOI
https://doi.org/10.1039/B211808D
Article type
Communication
Submitted
28 Nov 2002
Accepted
09 Jan 2003
First published
20 Jan 2003

Chem. Commun., 2003, 528-529

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The first NH aldimine organometallic compound. Isolation and crystal structure

J. Albert, J. M. Cadena, A. González, J. Granell, X. Solans and M. Font-Bardia, Chem. Commun., 2003, 528 DOI: 10.1039/B211808D

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