Issue 6, 2003
From the journal:

Chemical Communications

Gasification reaction of organic compounds catalyzed by RuO2 in supercritical water

Ki Chul Parkab  and  Hiroshi Tomiyasu*a  

* Corresponding authors

a Department of Chemistry and Material Engineering, Faculty of Engineering, Shinshu University, Wakasato, Nagano, Japan
E-mail: htomiya@gipwc.shinshu-u.ac.jp
Fax: +81 26 269 5425
Tel: +81 26 269 5425

b Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo, Japan

Abstract

Nearly complete gasification of organic compounds has been achieved by stoichiometrically insufficient amounts of RuO2 in supercritical water (SCW) to provide CH4, CO2 and H2, all the hydrogen atoms of which originate from water, and the catalytic effect of RuO2 results from a redox couple of RuIV/RuII induced by SCW.

Graphical abstract: Gasification reaction of organic compounds catalyzed by RuO2 in supercritical water

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Article information

DOI
https://doi.org/10.1039/B211800A
Article type
Communication
Submitted
04 Dec 2002
Accepted
06 Jan 2003
First published
17 Feb 2003

Chem. Commun., 2003, 694-695

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Gasification reaction of organic compounds catalyzed by RuO2 in supercritical water

K. C. Park and H. Tomiyasu, Chem. Commun., 2003, 694 DOI: 10.1039/B211800A

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