Issue 3, 2003
From the journal:

Chemical Communications

A novel three-dimensional coordination polymer constructed with mixed-valence dimeric copper(i,ii) units†

Ming-Liang Tong,ab   Li-Jun Li,ac   Katsunori Mochizuki,a   Ho-Chol Chang,a   Xiao-Ming Chen,b   Ying Lic  and  Susumu Kitagawa*a  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan
E-mail: kitagawa@sbchem.kyoto-u.ac.jp

b School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China

c National Laboratory of Applied Organic Chemistry, Institute of Organic Chemistry, Lanzhou University, Lanzhou 730000, China

Abstract

A novel three-dimensional coordination polymer with a mixed-valence localized copper(I,II) dimeric unit, [Cu2(4-pya)3]n (4-pya = 4-pyridinecarboxylate), was hydrothermally synthesized via a simultaneous in-situa redox and hydrolysis reaction of Cu(II) and 4-cyanopyridine and crystallographically characterized to be a twofold interpenetrated three-dimensional coordination network with a cubic [Cu16(4-pya)12] building unit.

Graphical abstract: A novel three-dimensional coordination polymer constructed with mixed-valence dimeric copper(i,ii) units

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Article information

DOI
https://doi.org/10.1039/B210914J
Article type
Communication
Submitted
06 Nov 2002
Accepted
17 Dec 2002
First published
15 Jan 2003

Chem. Commun., 2003, 428-429

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A novel three-dimensional coordination polymer constructed with mixed-valence dimeric copper(I,II) units

M. Tong, L. Li, K. Mochizuki, H. Chang, X. Chen, Y. Li and S. Kitagawa, Chem. Commun., 2003, 428 DOI: 10.1039/B210914J

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