Structural effects on sigmatropic shifts in heteroaromatic allyl ethers†
Abstract
In contrast to the known thermal, exclusively [3,3], O- to N- rearrangement of allyl groups in phenyltetrazoles (1, Scheme 1), the comparable migration of the
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* Corresponding authors
a
Universidade do Algarve, F.C.T., Química Biológica, Campus de Gambelas, Faro 8000, Portugal
E-mail:
mcristi@ualg.pt
Fax: +351 289819403
Tel: +351 289800100 ext. 7642
b
Department of Chemistry, University of Liverpool, Liverpool, UK
E-mail:
rj05@liv.ac.uk
Fax: +44 151 7943588
Tel: +44 151 7943502
In contrast to the known thermal, exclusively [3,3], O- to N- rearrangement of allyl groups in phenyltetrazoles (1, Scheme 1), the comparable migration of the
N. C. P. Araújo, P. M. M. Barroca, J. F. Bickley, A. F. Brigas, M. L. S. Cristiano, R. A. W. Johnstone, R. M. S. Loureiro and P. C. A. Pena, J. Chem. Soc., Perkin Trans. 1, 2002, 1213 DOI: 10.1039/B102674G
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