Issue 8, 2002
From the journal:

New Journal of Chemistry

Platinum(iv)-mediated coupling of dione monoximes and nitriles: a novel reactivity pattern of the classic oxime-based chelating ligands

Anastassiya V. Makarycheva-Mikhailova,a   Matti Haukka,b   Nadezhda A. Bokach,ac   Dmitrii A. Garnovskii,c   Mathea S. Galanski,d   Bernhard K. Keppler,*d   Armando J. L. Pombeiro*c  and  Vadim Yu. Kukushkin*a  

* Corresponding authors

a Department of Chemistry, St. Petersburg State University, Stary Petergof, Russian Federation
E-mail: kukushkin@VK2100.spb.edu

b Department of Chemistry, P.O. Box 111, Joensuu, Finland
E-mail: Matti.Haukka@Joensuu.fi

c Centro de Química Estrutural, Complexo I, Instituto Superior Técnico, Av. Rovisco Pais, Lisbon, Portugal
E-mail: pombeiro@ist.utl.pt

d Institute for Inorganic Chemistry, University of Vienna, Währinger Str. 42, Vienna, Austria
E-mail: keppler@merlin.ap.univie.ac.at

Abstract

The reaction between dione monoximes and platinum(IV) nitrile complexes leads, instead of the conventional substitution, to metal-mediated coupling, giving iminoacylated species which, on being liberated, undergo disintegration to the nitrile and the oxime.

Graphical abstract: Platinum(iv)-mediated coupling of dione monoximes and nitriles: a novel reactivity pattern of the classic oxime-based chelating ligands

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Article information

DOI
https://doi.org/10.1039/B202947B
Article type
Paper
Submitted
25 Mar 2002
Accepted
07 May 2002
First published
26 Jun 2002

New J. Chem., 2002,26, 1085-1091

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Platinum(IV)-mediated coupling of dione monoximes and nitriles: a novel reactivity pattern of the classic oxime-based chelating ligands

A. V. Makarycheva-Mikhailova, M. Haukka, N. A. Bokach, D. A. Garnovskii, M. S. Galanski, B. K. Keppler, A. J. L. Pombeiro and V. Yu. Kukushkin, New J. Chem., 2002, 26, 1085 DOI: 10.1039/B202947B

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