Issue 13, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Formation of a caged rhodium complex via an intramolecular, metal-mediated [2 + 2 + 1] cycloaddition of alkynes and CO†

Murray V. Baker,*a   David H. Brown,a   Brian W. Skeltona  and  Allan H. Whitea  

* Corresponding authors

a Department of Chemistry, The University of Western Australia, 35 Stirling Hwy, Crawley, WA 6009, Australia
E-mail: mvb@chem.uwa.edu.au

Abstract

An organometallic rhodium cage complex has been synthesized by a metal-mediated intramolecular [2 + 2 + 1] cycloaddition, in the first example of such a process where the cyclisation step completes a cage around the metal centre.

Graphical abstract: Formation of a caged rhodium complex via an intramolecular, metal-mediated [2 + 2 + 1] cycloaddition of alkynes and CO

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Article information

DOI
https://doi.org/10.1039/B202713E
Article type
Communication
Submitted
18 Mar 2002
Accepted
20 May 2002
First published
30 May 2002

J. Chem. Soc., Dalton Trans., 2002, 2595-2596

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Formation of a caged rhodium complex via an intramolecular, metal-mediated [2 + 2 + 1] cycloaddition of alkynes and CO

M. V. Baker, D. H. Brown, B. W. Skelton and A. H. White, J. Chem. Soc., Dalton Trans., 2002, 2595 DOI: 10.1039/B202713E

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