Issue 3, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Novel dicarbonyl and carbonylnitrosyl tris(μ-triazenide) dirhodium complexes

Neil G. Connelly,a   Owen D. Hayward,a   Phimphaka Klangsinsirikula  and  A. Guy Orpena  

a School of Chemistry, University of Bristol, Bristol, UK

Abstract

The first neutral, tribridged [Rh2]3+ triazenide complex, [(OC)Rh(μ-RNNNR)3Rh(CO)] (R = C6H4Me-p), reacts with NO gas to give the novel nitrosyl [(OC)Rh(μ-RNNNR)3Rh(NO)] with an [Rh2]4+ core linked to NO−.

Graphical abstract: Novel dicarbonyl and carbonylnitrosyl tris(μ-triazenide) dirhodium complexes

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Article information

DOI
https://doi.org/10.1039/B109972H
Article type
Communication
Submitted
31 Oct 2001
Accepted
04 Dec 2001
First published
17 Dec 2001

J. Chem. Soc., Dalton Trans., 2002, 305-306

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Novel dicarbonyl and carbonylnitrosyl tris(μ-triazenide) dirhodium complexes

N. G. Connelly, O. D. Hayward, P. Klangsinsirikul and A. G. Orpen, J. Chem. Soc., Dalton Trans., 2002, 305 DOI: 10.1039/B109972H

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