Issue 7, 2002
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis and structural study of late transition metal complexes of N-[(diphenylphosphino)methyl]-2-pyridinamine and N-cyclohexyl-N-[(diphenylphosphino)methyl]-2-pyridinamine

Hai-Bin Song,a   Zheng-Zhi Zhangb  and  Thomas C. W. Mak*a  

* Corresponding authors

a Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, P. R. China
E-mail: tcwmak@cuhk.edu.hk

b State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin, P. R. China

Abstract

The reaction of N-[(diphenylphosphino)methyl]-2-pyridinamine and N-cyclohexyl-N-[(diphenylphosphino)methyl]-2-pyridinamine with palladium(II), copper(I) and silver(I) salts and iron pentacarbonyl in different stoichiometric ratios yielded a series of complexes that display various coordination modes, including a novel P,N(amine),N(pyridyl)-bridging mode in a dinuclear silver complex which is consolidated by the argentophilic interaction.

Graphical abstract: Synthesis and structural study of late transition metal complexes of N-[(diphenylphosphino)methyl]-2-pyridinamine and N-cyclohexyl-N-[(diphenylphosphino)methyl]-2-pyridinamine

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Article information

DOI
https://doi.org/10.1039/B109191N
Article type
Paper
Submitted
09 Oct 2001
Accepted
23 Jan 2002
First published
07 Mar 2002

J. Chem. Soc., Dalton Trans., 2002, 1336-1343

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Synthesis and structural study of late transition metal complexes of N-[(diphenylphosphino)methyl]-2-pyridinamine and N-cyclohexyl-N-[(diphenylphosphino)methyl]-2-pyridinamine

H. Song, Z. Zhang and T. C. W. Mak, J. Chem. Soc., Dalton Trans., 2002, 1336 DOI: 10.1039/B109191N

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