Stereochemical effects on the spin-state transition shown by salts of [FeL2]2+ [L = 2,6-di(pyrazol-1-yl)pyridine]
Abstract
The syntheses of [Fe(L1H)2]X2 (L1H = 2,6-di(pyrazol-1-yl)pyridine [L1H]; X−
= BF4−, PF6−) are described.
* Corresponding authors
a
School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, UK
E-mail:
M.A.Halcrow@chem.leeds.ac.uk
b Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK
c Interdisciplinary Research Centre in Superconductivity, University of Cambridge, Madingley Road, Cambridge, UK
d
Department of Chemistry, University of Hull, Kingston-Upon-Hull, UK
E-mail:
A.J.Bridgeman@hull.ac.uk
The syntheses of [Fe(L1H)2]X2 (L1H = 2,6-di(pyrazol-1-yl)pyridine [L1H]; X−
= BF4−, PF6−) are described.
J. M. Holland, J. A. McAllister, C. A. Kilner, M. Thornton-Pett, A. J. Bridgeman and M. A. Halcrow, J. Chem. Soc., Dalton Trans., 2002, 548 DOI: 10.1039/B108468M
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