Issue 21, 2002
From the journal:

Chemical Communications

High-valent metalloporphyrin, Fe(tpp)OTf, catalyzed rearrangement of α,β-epoxy ketones into 1,2-diketones

Kohji Suda,*a   Kenji Baba,a   Shin-ichiro Nakajimaa  and  Toshikatsu Takanamia  

* Corresponding authors

a Meiji Pharmaceutical University, 2-522-1, Noshio, Kiyose, Tokyo, Japan
E-mail: suda@my-pharm.ac.jp
Fax: +81 (424)-95-8780

Abstract

Iron(III) tetraphenylporphyrin triflate, Fe(tpp)OTf, works as an efficient and characteristic Lewis acid catalyst in the selective rearrangement of α,β-epoxy ketones into 1,2-diketones.

Graphical abstract: High-valent metalloporphyrin, Fe(tpp)OTf, catalyzed rearrangement of α,β-epoxy ketones into 1,2-diketones

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Article information

DOI
https://doi.org/10.1039/B207328E
Article type
Communication
Submitted
26 Jul 2002
Accepted
23 Sep 2002
First published
07 Oct 2002

Chem. Commun., 2002, 2570-2571

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High-valent metalloporphyrin, Fe(tpp)OTf, catalyzed rearrangement of α,β-epoxy ketones into 1,2-diketones

K. Suda, K. Baba, S. Nakajima and T. Takanami, Chem. Commun., 2002, 2570 DOI: 10.1039/B207328E

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