Issue 21, 2002
From the journal:

Chemical Communications

Experimental and computational study of a reductive elimination mechanism in a methyl–Pd(ii)–CNC carbene complex

David J. Nielsen,a   Alison M. Magill,a   Brian F. Yates,a   Kingsley J. Cavell,*b   Brian W. Skeltonc  and  Allan H. Whitec  

* Corresponding authors

a University of Tasmania, GPO Box 252-75, Hobart, 7005, Tasmania, Australia

b Department of Chemistry, Cardiff University, PO Box 912, Cardiff, UK
E-mail: cavellkj@cf.ac.uk
Fax: +44 29 20875899

c Chemistry, University of Western Australia, Crawley, Western Australia, 6009, Australia

Abstract

Experimental and density functional studies on the decomposition of a novel palladium–methyl complex of the rigid CNC ligand 2,6-bis(1-alkylimidazolin-2-yliden-3-yl)pyridine show that reductive elimination to give 2-methylimidazolium species is a facile reaction.

Graphical abstract: Experimental and computational study of a reductive elimination mechanism in a methyl–Pd(ii)–CNC carbene complex

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Article information

DOI
https://doi.org/10.1039/B207020K
Article type
Communication
Submitted
18 Jul 2002
Accepted
11 Sep 2002
First published
25 Sep 2002

Chem. Commun., 2002, 2500-2501

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Experimental and computational study of a reductive elimination mechanism in a methyl–Pd(II)–CNC carbene complex

D. J. Nielsen, A. M. Magill, B. F. Yates, K. J. Cavell, B. W. Skelton and A. H. White, Chem. Commun., 2002, 2500 DOI: 10.1039/B207020K

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