Issue 15, 2002

Silazanes/catalytic bases: mild, powerful and chemoselective agents for the preparation of enolsilyl ethers from ketones and aldehydes

Abstract

We have developed an efficient method for the preparation of enol silyl ethers using novel agents, silazanes together with NaH or DBU catalyst, wherein TMS and TBDMS groups were smoothly and chemoselectively introduced into ketones and aldehydes under mild conditions.

Graphical abstract: Silazanes/catalytic bases: mild, powerful and chemoselective agents for the preparation of enol silyl ethers from ketones and aldehydes

Article information

Article type
Communication
Submitted
18 Apr 2002
Accepted
05 Jun 2002
First published
28 Jun 2002

Chem. Commun., 2002, 1628-1629

Silazanes/catalytic bases: mild, powerful and chemoselective agents for the preparation of enol silyl ethers from ketones and aldehydes

Y. Tanabe, T. Misaki, M. Kurihara, A. Iida and Y. Nishii, Chem. Commun., 2002, 1628 DOI: 10.1039/B203783C

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