Issue 4, 2002
From the journal:

Chemical Communications

Mixed nitrosyl/phosphinidene and nitrene/phosphinidene clusters of ruthenium†

Ludmila Scoles,a   Brian T. Sterenberg,a   Konstantin A. Udachina  and  Arthur J. Carty*a  

* Corresponding authors

a Steacie Institute for Molecular Sciences, National Research Council Canada, 100 Sussex Drive, Ottawa, Ontario, Canada

b Ottawa-Carleton Chemistry Research Institute, Dept. of Chemistry, University of Ottawa, Ottawa, Ontario, Canada
E-mail: Arthur.Carty@urc.ca

Abstract

Reaction of the aminophosphinidene complex [Ru5(CO)15(μ4-PNPri2)] 1 with [PPN][NO2] (PPN = Ph3P[double bond, length as m-dash]N[double bond, length as m-dash]PPh3) led to the mixed nitrosyl/phosphinidene cluster complex [PPN][Ru5(CO)13(μ-NO)(μ4-PNPri2)] 2 which is transformed into the novel nitrene/phosphinidene cluster [Ru5(CO)10(μ-CO)2(μ3-CO)(μ4-NH)(μ3-PNPri2)] 3via treatment with triflic acid.

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Article information

DOI
https://doi.org/10.1039/B110927H
Article type
Communication
Submitted
27 Nov 2001
Accepted
03 Jan 2002
First published
31 Jan 2002

Chem. Commun., 2002, 320-321

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Mixed nitrosyl/phosphinidene and nitrene/phosphinidene clusters of ruthenium

L. Scoles, B. T. Sterenberg, K. A. Udachin and A. J. Carty, Chem. Commun., 2002, 320 DOI: 10.1039/B110927H

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