Issue 4, 2001
From the journal:

New Journal of Chemistry

Homobinuclear complexes of osmium(IV) with nitrogen-containing π-conjugated bridging units

Andrei Maiborodaa  and  Heinrich Lang*a  

* Corresponding authors

a Lehrstuhl für Anorganische Chemie, Institut für Chemie, Fakultät für Naturwissenschaften, Technische Uniersität Chemnitz, Straße der Nationen 62, Chemnitz, Germany
E-mail: heinrich.lang@chemie.tu-chemnitz.de

Abstract

The synthesis as well as chemical and physical properties of anionic homobinuclear osmium(IV) complexes of the general type [AsPh4]2[OsCl5(LL)OsCl5] [LL =  pyrazine (6), 4,4′-bipyridine (7), 1,4-dicyanobenzene (8) and 4-cyanopyridine (9)] is described. While 6 and 9 exhibit strong (6) or weak (9) intramolecular electronic communication between the Os(IV) centres, in 7 and 8 the metals can be considered non-interacting.

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Article information

DOI
https://doi.org/10.1039/B007619H
Article type
Paper
Submitted
15 Sep 2000
Accepted
20 Dec 2000
First published
15 Mar 2001

New J. Chem., 2001,25, 642-646

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Homobinuclear complexes of osmium(IV) with nitrogen-containing π-conjugated bridging units

A. Maiboroda and H. Lang, New J. Chem., 2001, 25, 642 DOI: 10.1039/B007619H

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