Issue 1, 2001
From the journal:

New Journal of Chemistry

Fluorine-containing α-alkynyl amino esters and access to a new family of 3,4-dehydroproline analogues†

David Sémeril,a   Jérôme Le Nôtre,a   Christian Bruneau,a   Pierre H. Dixneuf,*a   Alexey F. Kolomietsb  and  Sergey N. Osipov*b  

* Corresponding authors

a Laboratoire d'Organométalliques et Catalyse: Chimie et Electrochimie Moléculaires (CNRS UMR 6509), Uniersité de Rennes, Campus de Beaulieu, Rennes, France
E-mail: pierre.dixneuf@univ-rennes1.fr

b A N Nesmeyano Institute of Organoelement Compounds, Russian Academy of Sciences, Vailo str. 28, Moscow, V-334, GSP-1, Russia
E-mail: osipov@ineos.ac.ru

Abstract

New α-alkynyl, α-CF3 amino esters have been prepared from electrophilic imines and used to produce 3-alkenyl-3,4-dehydroproline derivatives, [italic v (to differentiate from Times ital nu)]ia enyne metathesis with the precatalyst [Ru[double bond, length half m-dash]C[double bond, length half m-dash]C[double bond, length half m-dash]CPh2(Cl)(PCy3)(arene)]O3SCF3. These new conjugated fluorine-containing dienes are active substrates for the Diels–Alder reaction and lead to a new class of bicyclic amino esters.

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Article information

DOI
https://doi.org/10.1039/B007396M
Article type
Letter
Submitted
06 Sep 2000
Accepted
11 Oct 2000
First published
08 Dec 2000

New J. Chem., 2001,25, 16-18

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Fluorine-containing α-alkynyl amino esters and access to a new family of 3,4-dehydroproline analogues

D. Sémeril, J. Le Nôtre, C. Bruneau, P. H. Dixneuf, A. F. Kolomiets and S. N. Osipov, New J. Chem., 2001, 25, 16 DOI: 10.1039/B007396M

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