Issue 17, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

(CN3H6)2·Zn(HPO3)2: An open-framework zincophosphite built up from polyhedral 12-rings

William T. A. Harrison,*a   Mark L. F. Phillipsb  and  Tina M. Nenoffc  

* Corresponding authors

a Department of Chemistry, University of Aberdeen, Aberdeen, UK
E-mail: w.harrison@abdn.ac.uk

b 27468 Hayward Boulevard, Hayward, USA

c Sandia National Laboratories, Environmental Monitoring & Characterization, PO Box 5800, MS 0755, Albuquerque, USA

Abstract

The solution-mediated synthesis and single crystal structure of (CN3H6)2·Zn(HPO3)2 are reported. This phase is built up from a three-dimensional framework of vertex-linked ZnO4 and HPO3 building units encapsulating the extra-framework guanidinium cations. The structure is stabilised by template-to-framework hydrogen bonding. The inorganic framework contains polyhedral 12-rings and shows a surprising similarity to those of some known organically-templated zinc phosphates.

Graphical abstract: (CN3H6)2·Zn(HPO3)2: An open-framework zincophosphite built up from polyhedral 12-rings

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Article information

DOI
https://doi.org/10.1039/B102007M
Article type
Paper
Submitted
02 Mar 2001
Accepted
09 Jul 2001
First published
09 Aug 2001

J. Chem. Soc., Dalton Trans., 2001, 2459-2461

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(CN3H6)2·Zn(HPO3)2: An open-framework zincophosphite built up from polyhedral 12-rings

W. T. A. Harrison, M. L. F. Phillips and T. M. Nenoff, J. Chem. Soc., Dalton Trans., 2001, 2459 DOI: 10.1039/B102007M

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