Issue 16, 2001
From the journal:

Chemical Communications

Beyond Fe-only hydrogenases: N-functionalized 2-aza-1,3-dithiolates Fe2[(SCH2)2NR](CO)x (x = 5, 6)

Joshua D. Lawrence,a   Hongxiang Lia  and  Thomas B. Rauchfuss*a  

* Corresponding authors

a Department of Chemistry, University of Illinois, 601 S. Goodwin Ave., Urbana, IL, USA.
E-mail: rauchfuz@uiuc.edu

Abstract

Primary amines undergo chloromethylation with CH2O/SOCl2 to give RN(CH2Cl)2, which in turn react with Li2[Fe2S2(CO)6] to give Fe2[(SCH2)2NR](CO)6; in the case of R = CH2CH[double bond, length half m-dash]CH2 and CH2CH2SMe, Me3NO-induced decarbonylation afforded pentacarbonyl derivatives wherein the pendant functionality is coordinated to Fe.

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Article information

DOI
https://doi.org/10.1039/B104195A
Article type
Communication
Submitted
14 May 2001
Accepted
26 Jun 2001
First published
23 Jul 2001

Chem. Commun., 2001, 1482-1483

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Beyond Fe-only hydrogenases: N-functionalized 2-aza-1,3-dithiolates Fe2[(SCH2)2NR](CO)x (x = 5, 6)

J. D. Lawrence, H. Li and T. B. Rauchfuss, Chem. Commun., 2001, 1482 DOI: 10.1039/B104195A

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