Reaction between BiX2Ph (X = Cl or I) and 4,4'-bipy afforded crystals of complexes trans-[BiX2Ph(4,4'-bipy)]n as solvates in which an anticipated combination of dative (Bi?bipy) and secondary bonding (Bi⋯X) leads to a controlled polymeric structure.
S. C. James, N. C. Norman, A. Guy Orpen and J. Starbuck, CrystEngComm, 2000, 2, 67 DOI: 10.1039/B001874K
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