Thiophene S-binding of a conformationally constrained thiophenophane leading to the formation of a copper(I) coordination polymer

Lyall R. Hanton; Christopher Richardson; Ward T. Robinson; Julia M. Turnbull

doi:10.1039/B007579P

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Thiophene S-binding of a conformationally constrained thiophenophane leading to the formation of a copper(i) coordination polymer

Lyall R. Hanton,*^a Christopher Richardson,^b Ward T. Robinson^b and Julia M. Turnbull^a

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* Corresponding authors

^a Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.
E-mail: lhanton@alkali.otago.ac.nz

^b Department of Chemistry, University of Canterbury, Private Bag 4800, Christchurch, New Zealand

Abstract

The potentially tetradentate NS₃ thiophenophane binds strongly to Cu(I) through a thiophene S, pyridine N and one thioether S, leaving the remaining thioether S donor in an exodentate arrangement forming an infinite polymeric link between Cu(I) atoms.

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Supplementary files

Crystal structure data TXT (20K)

Article information

DOI: https://doi.org/10.1039/B007579P
Article type: Communication
Submitted: 18 Sep 2000
Accepted: 06 Nov 2000
First published: 30 Nov 2000

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Chem. Commun., 2000, 2465-2466

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Thiophene S-binding of a conformationally constrained thiophenophane leading to the formation of a copper(I) coordination polymer

L. R. Hanton, C. Richardson, W. T. Robinson and J. M. Turnbull, Chem. Commun., 2000, 2465 DOI: 10.1039/B007579P

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Chemical Communications

Thiophene S-binding of a conformationally constrained thiophenophane leading to the formation of a copper(i) coordination polymer

Abstract

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Thiophene S-binding of a conformationally constrained thiophenophane leading to the formation of a copper(I) coordination polymer

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