Issue 8, 2000
From the journal:

Chemical Communications

A ring-closing metathesis-mediated route to novel enantiopure conformationally restricted cyclic amino acidsElectronic supplementary information (ESI) available: characterisation data for compounds 7, 9 and 16. See http://www.rsc.org/suppdata/cc/b0/b001253j/

Kim C. M. F. Tjen,a   Sape S. Kinderman,a   Hans E. Schoemaker,b   Henk Hiemstraa  and  Floris P. J. T. Rutjes*a  

* Corresponding authors

a Institute of Molecular Chemistry, University of Amsterdam, Nieuwe Achtergracht 129, Amsterdam, The Netherlands

b Department of Organic Chemistry and Biotechnology, DSM Research, P.O. Box 18, Geleen, The Netherlands

c Department of Organic Chemistry, University of Nijmegen, Toernooiveld 1, Nijmegen, The Netherlands

Abstract

A combination of palladium-catalysed N,O-acetal formation, ruthenium-catalysed ring-closing metathesis and N-sulfonyliminium ion-mediated C–C bond formation constitutes an efficient and versatile route to a set of enantiomerically pure 2,6-disubstituted unsaturated pipecolic acid derivatives.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/B001253J
Article type
Communication
Submitted
15 Feb 2000
Accepted
15 Mar 2000
First published
04 Apr 2000

Chem. Commun., 2000, 699-700

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A ring-closing metathesis-mediated route to novel enantiopure conformationally restricted cyclic amino acids

K. C. M. F. Tjen, S. S. Kinderman, H. E. Schoemaker, H. Hiemstra and F. P. J. T. Rutjes, Chem. Commun., 2000, 699 DOI: 10.1039/B001253J

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