The synthesis and crystal structure of decanuclear Co and nonanuclear Ni cages are reported: the cages feature carboxylate and pyridonate ligands and demonstrate that inter-ligand repulsions can lead to novel structures.
Changing cage structures through inter-ligand repulsions
A. Graham, S. Meier, S. Parsons and R. E. P. Winpenny, Chem. Commun., 2000, 811 DOI: 10.1039/B000385I
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