Issue 7, 2000
From the journal:

Chemical Communications

Chemistry of M(allyl)3 (M = Rh, Ir) compounds: structural characterization of tris(allyl)iridium complexes with phosphorus ligandsElectronic supplementary information (ESI) available: preparative details and NMR data for 1–6 and crystallographic data for 1, 3 and 4. See http://www.rsc.org/suppdata/cc/a9/a910164k/

Kevin D. John,a   Kenneth V. Salazar,b   Brian L. Scott,a   R. Thomas Baker*a  and  Alfred P. Sattelberger*a  

* Corresponding authors

a Los Alamos Catalysis Initiative, Chemical Science and Technology Division, Los Alamos National Laboratory, MS J514, Los Alamos, USA.
E-mail: weg@lanl.gov; sattelberger@lanl.gov

b Materials Science and Technology Division, Los Alamos National Laboratory, MS E549, Los Alamos, USA

Abstract

While addition of phosphorus ligands such as P(OPh)3 to Rh(allyl)3 gives monovalent Rh(allyl)L2, the iridium analog gives stable mixed σ/π-tris(allyl) complexes, as evidenced by the structural characterization of mono-, bi-, and tri-dentate ligand complexes.

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Supplementary files

Article information

DOI
https://doi.org/10.1039/A910164K
Article type
Communication
Submitted
21 Dec 1999
Accepted
22 Feb 2000
First published
21 Mar 2000

Chem. Commun., 2000, 581-582

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Chemistry of M(allyl)3 (M = Rh, Ir) compounds: structural characterization of tris(allyl)iridium complexes with phosphorus ligands

K. D. John, K. V. Salazar, B. L. Scott, R. T. Baker and A. P. Sattelberger, Chem. Commun., 2000, 581 DOI: 10.1039/A910164K

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