The enone 1 was oxidized stereoselectively using urea-hydrogen peroxide with polyeucine as the catalyst to give the epoxide 2 which was used to make (+)-goniotriol 7, (+)-goniofufurone 8, (+)-8-acetylgonitriol 9 and gonio-pypyrone 10.
W. Chen and S. M. Roberts, J. Chem. Soc., Perkin Trans. 1, 1999, 103 DOI: 10.1039/A808436J
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