A rhodium complex supported on polyvinylpyrrolidone catalyses the carbonylation of methanol to methyl ethanoate and ethanoic acid in supercritical CO2 at rates up to ca. 50% those in liquid solution but with minimal catalyst leaching.
R. J. Sowden, M. F. Sellin, N. De Blasio and D. J. Cole-Hamilton, Chem. Commun., 1999, 2511 DOI: 10.1039/A906653E
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