Issue 18, 1999

Et2Zn as a base: zinc enolate free from other metals significantly enhances the enantiomeric excess in palladium-catalyzed allylic alkylation

Abstract

The enantiomeric excess of palladium-catalyzed allylic alkylations was greatly increased when Et2Zn was used as the base to generate an anion from malonates.

Article information

Article type
Paper

Chem. Commun., 1999, 1895-1896

Et2Zn as a base: zinc enolate free from other metals significantly enhances the enantiomeric excess in palladium-catalyzed allylic alkylation

K. Fuji, N. Kinoshita and K. Tanaka, Chem. Commun., 1999, 1895 DOI: 10.1039/A906034K

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