IR spectroscopic results, combined with earlier crystallographic and spectroscopic evidence on Fe and Ru nitrosyl complexes, indicate that metastable η1-O and η2-NO linkage isomers are formed on low-temperature irradiation of the nitrosyl metalloporphyrins (OEP)Ru(NO)L (L = O-i-C5H11, SCH2CF3); the new compounds are stable at low temperature, but revert to the ground state on warming.
D. V. Fomitchev, P. Coppens, T. Li, K. A. Bagley, L. Chen and G. B. Richter-Addo, Chem. Commun., 1999, 2013 DOI: 10.1039/A905285B
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