The combination of RuCl2(PPh3)3 and TEMPO affords an efficient catalytic system for the aerobic oxidation of a broad range of primary and secondary (aliphatic) alcohols at 100 °C, giving the corresponding aldehydes and ketones, respectively, in >99% selectivity in all cases.
A. Dijksman, I. W. C. E. Arends and R. A. Sheldon, Chem. Commun., 1999, 1591 DOI: 10.1039/A902594D
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