The metallo-diethynylbenzene complex W(![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CC6H4CCH-4)(dmpe)2Cl, a precursor to metal-containing poly(phenyleneethynylene)s, has been prepared using alkyne-metathesis methodology and can be coupled into unsaturated organic frameworks at both the ethynyl moiety and the tungsten center and one-electron oxidized to the open-shell cation.
K. D. John and M. D. Hopkins, Chem. Commun., 1999, 589 DOI: 10.1039/A809231A
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