On treatment with ButLi in the presence of HMPA, N-benzylbenzamides undergo anionic cyclisation with dearomatisation to give an extended amide enolate which reacts with electrophiles to yield bicyclic cyclohexadiene derivatives.
A. Ahmed, J. Clayden and S. A. Yasin, Chem. Commun., 1999, 231 DOI: 10.1039/A808218I
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