Issue 1, 1999

Tributyltin radical-induced addition–carbocyclization on chiral perhydro-1,3-benzoxazines: a facile entry to enantiopure tin-containing auxiliaries

Abstract

N-Acryloylperhydro-1,3-benzoxazines 1a,b undergo stereo-selective addition–carbocyclization when reacted with Bu3SnH, leading to stannylated lactamic rings that can be transformed into enantiopure pyrrolidines.

Article information

Article type
Paper

Chem. Commun., 1999, 31-32

Tributyltin radical-induced addition–carbocyclization on chiral perhydro-1,3-benzoxazines: a facile entry to enantiopure tin-containing auxiliaries

C. Andrés, J. Pablo Duque-Soladana and R. Pedrosa, Chem. Commun., 1999, 31 DOI: 10.1039/A807773H

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