Issue 15, 1998
From the journal:

Chemical Communications

Rare M7O2 double tetrahedral core in molecular species: preparation, structure and properties of [Zn7O2(O2CMe)10(1-Meim)2] (1-Meim = 1-methylimidazole)

Nikolia Lalioti,   Spyros P. Perlepes,   Evy Manessi-Zoupa,   Catherine P. Raptopoulou,   Aris Terzis,   Abil E. Aliev  and  Ioannis P. Gerothanassis  

Abstract

The 2:1 reaction between Zn(O2CMe)2·2H2O and 1-Meim in refluxing MeCN gives [Zn7O2(O2CMe)10(1-Meim)2] 1 which comprises two vertex-sharing tetranuclear Zn4(µ4-O)(η1: η1:µ2-O2CMe)5(1-Meim) units; solid-state 13C and 15N NMR spectra reveal structural details of the complex.

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Article information

DOI
https://doi.org/10.1039/A802844C
Article type
Paper

Chem. Commun., 1998, 1513-1514

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Rare M7O2 double tetrahedral core in molecular species: preparation, structure and properties of [Zn7O2(O2CMe)10(1-Meim)2] (1-Meim = 1-methylimidazole)

N. Lalioti, S. P. Perlepes, E. Manessi-Zoupa, C. P. Raptopoulou, A. Terzis, A. E. Aliev and I. P. Gerothanassis, Chem. Commun., 1998, 1513 DOI: 10.1039/A802844C

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