Issue 11, 1998

Rearrangement of o-(chloromethyldimethylsilyl)phenylmethoxide: evidence for an apical position of the migrating group in a trigonal bipyramid intermediate

Abstract

Chloromethylsilane 5a undergoes a rearrangement reaction to give oxasilacyclopentane 9 rather than oxasilacyclohexane 10, indicating that the methyl group migrates in preference to the aryl group.

Article information

Article type
Paper

Chem. Commun., 1998, 1213-1214

Rearrangement of o-(chloromethyldimethylsilyl)phenylmethoxide: evidence for an apical position of the migrating group in a trigonal bipyramid intermediate

Y. M. Hijji, P. F. Hudrlik and A. M. Hudrlik, Chem. Commun., 1998, 1213 DOI: 10.1039/A801377B

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