Issue 4, 1998
From the journal:

New Journal of Chemistry

16-Electron, non-π-stabilized Ir(H)2(H2)(PBu2tPh)2+ and 18-electron Ir(H)2(H2)2(PBu2tPh)2+: fluxionality and H/D exchange as independent processes

Alan C. Cooper,   Odile Eisenstein  and  Kenneth G. Caulton  

Abstract

Variable-temperature 1H NMR studies and abinitio (B3LYP) calculations have revealed hydride site exchange in [Ir(H)2(H2)(PBu2tPh)2][BAr4′] [Ar′=C6H3(CF3)2-3,5] as well as fluxional and HD formation processes in [Ir(H)2(H2)2(PBu2tPh)2][BAr4′] that occur via independent mechanisms.

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Article information

DOI
https://doi.org/10.1039/A801330F
Article type
Paper

New J. Chem., 1998,22, 307-310

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16-Electron, non-π-stabilized Ir(H)2(H2)(PBu2tPh)2+ and 18-electron Ir(H)2(H2)2(PBu2tPh)2+: fluxionality and H/D exchange as independent processes

A. C. Cooper, O. Eisenstein and K. G. Caulton, New J. Chem., 1998, 22, 307 DOI: 10.1039/A801330F

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