Two new pentaerythritol-functionalised 2,2′:6′,2″-terpyridine (tpy) derivatives have been prepared. One contains four tpy metal-binding domains, whereas the other contains one tpy domain and three pendant CH2OH groups. The combination of these components with ruthenium-containing building blocks has allowed the specific and stepwise synthesis of tetranuclear and hexadecanuclear metallodendrimers.
E. C. Constable, C. E. Housecroft, M. Cattalini and D. Phillips, New J. Chem., 1998, 22, 193 DOI: 10.1039/A708320C
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