Crystal structures of the dicarbonyl 1,12-B12H10(CO)2 and its hydrated form 1,12-B12H10(CO2H2)2·4H2O show little π-bond character in their B–C bonds but contain significant distortions from the regular B12 icosahedron geometry; the hydrate, until now thought to be a hydroxonium salt, contains dihydroxycarbene (‘protonated carboxylic acid’) ligands C(OH)2.
M. A. Fox, J. A. K. Howard, J. M. Moloney and K. Wade, Chem. Commun., 1998, 2487 DOI: 10.1039/A806898D
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