High-melting phosphonium tosylates are synthesised and applied for the first time as solvents in catalytic hydroformylation reactions; variation in the substituents attached to phosphorus can lead to markedly different results; the catalyst systems are non-corrosive, easily manipulated and can readily be recovered and reused.
N. Karodia, S. Guise, C. Newlands and J. Andersen, Chem. Commun., 1998, 2341 DOI: 10.1039/A805376F
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