The most uncommon tricyclic sesquiterpenes, kelsoene 1 and prespatane 2, were isolated from cultured cells of liverwort Ptychanthus striatus, and the labelling patternof kelsoene biosynthesized from exogenous [2-13C]-mevalonate suggested that kelsoene is biosynthesized from germacradienyl cation via alloaromadendranyl cation.
K. Nabeta, K. Yamamoto, M. Hashimoto, M. Hashimoto, H. Koshino, K. Funatsuki and K. Katoh, Chem. Commun., 1998, 1485 DOI: 10.1039/A802908C
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