A dioxoruthenium(VI) complex with a D4-chiral porphyrin ligand has been prepared and characterized by spectroscopic methods and X-ray crystal analysis; the complex exhibits catalytic activity towards aerobic enantioselective epoxidation of prochiral alkenes with enantioselectivity up to 73% ee at an oxygen pressure of 8 atm.
T. Lai, R. Zhang, K. Cheung, C. Che, T. Lai and H. Kwong, Chem. Commun., 1998, 1583 DOI: 10.1039/A802009D
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