The macrolide rutamycin B containing 17 stereogenic centres and a 26-membered ring was synthesized by a route which features a chelate-controlled, double differentiating aldol reaction and ring closure by means of a vinyl–vinyl coupling.
J. D. White, R. W. Jackson and R. Hanselmann, Chem. Commun., 1998, 79 DOI: 10.1039/A707251A
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