Issue 2, 1997

An unusually large kinetic Br/Cl leaving group effect for the solvolysis of 1-halospiro[adamantane-2,2′-adamantane]

Abstract

The very large kBr/kCl leaving group effects of 2300–4500 for solvolysis of 1-halospiro[adamantane-2,2′-adamantane] compounds in slightly ethanolic or aqueous acetone are consistent with the occurrence of F-strain.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1997, 131-132

An unusually large kinetic Br/Cl leaving group effect for the solvolysis of 1-halospiro[adamantane-2,2′-adamantane]

D. N. Kevill, M. J. D’Souza and J. S. Lomas, J. Chem. Soc., Perkin Trans. 2, 1997, 131 DOI: 10.1039/A607628I

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